Cyanoferrocene
- Product Name
- Cyanoferrocene
- CAS No.
- 1273-84-3
- Chemical Name
- Cyanoferrocene
- Synonyms
- Cyanoferrocene;Ferrocene, cyano-;Ferrocenylnitrile;Ferrocenyl cyanide;Cyclopentadienecarbonitrile, cyclopentadienyliron deriv.
- CBNumber
- CB21457014
- Molecular Formula
- C6H4N.C5H5.Fe
- Formula Weight
- 211.044
- MOL File
- 1273-84-3.mol
Cyanoferrocene Property
- Melting point:
- 107-108℃
N-Bromosuccinimide Price
- Product number
- OGM0003544
- Product name
- CYANOFERROCENE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $498.71
- Updated
- 2021/12/16
- Product number
- AS517933
- Product name
- Cyanoferrocene
- Purity
- 98%
- Packaging
- 250mg
- Price
- $17
- Updated
- 2021/12/16
- Product number
- AS517933
- Product name
- Cyanoferrocene
- Purity
- 98%
- Packaging
- 1g
- Price
- $42
- Updated
- 2021/12/16
- Product number
- AS517933
- Product name
- Cyanoferrocene
- Purity
- 98%
- Packaging
- 5g
- Price
- $163
- Updated
- 2021/12/16
Cyanoferrocene Chemical Properties,Usage,Production
Description
Cyanoferrocene, [Fe(C5H5)(C6H4N)], forms sheets through hydrogen bonding. The N atom in the molecule accepts hydrogen bonds from C-H bonds in two other molecules, resulting in each molecule being hydrogen-bonded to four others. cyanoferrocene has occupied an important position since it can be converted to a structurally diverse set of ferrocenyl compounds that are attractive synthetic targets due to their chemical and biological properties.
Preparation
The synthesis of cyanoferrocene involved treating 3.1g (0.01 mol) of iodoferrocene and 3.6g (0.04 mol) of copper(I) cyanide with 20 ml of pyridine, using the same procedure used for preparing chloroferrocene. The resulting crude product was purified by chromatography on Florisil, yielding 1.75 g of cyanoferrocene with a yield of 83%. The melting point of cyanoferrocene was 106-107°C (lit. 107-108°C). A by-product of unidentified yellow crystals was also obtained, weighing 0.15g with a melting point of 157-158°C.
References
The Reaction of Haloferrocenes with Copper(Ⅰ) Salts
DOI: 10.1246/bcsj.42.1976
Cyanoferrocene: a Two-Dimensional Network Generated by Short C-H...N Hydrogen Bonds
DOI: 10.1107/S0108270196006233
Efficient one-pot synthesis of cyanoferrocene from ferrocenecarboxaldehyde using NH2OH · HCl/KI/ZnO/CH3CN system
DOI: 10.1016/j.jorganchem.2007.02.002
Cyanoferrocene Preparation Products And Raw materials
Raw materials
Preparation Products
Cyanoferrocene Suppliers
- Tel
- +1-833-552-7181
- sales@aladdinsci.com
- Country
- United States
- ProdList
- 57511
- Advantage
- 58